Câu 3 : 

\(n_{HCl}=\dfrac{10\cdot21.9\%}{36.5}=0.06\left(mol\right)\)

\(AO+2HCl\rightarrow ACl_2+H_2O\)

\(0.03........0.06\)

\(M=\dfrac{2.4}{0.03}=80\left(\dfrac{g}{mol}\right)\)

\(\Rightarrow A=64\)

\(CuO\)

Câu 2 : 

$n_{CuO} = \dfrac{1,6}{80} = 0,02(mol)$
$n_{H_2SO_4} = \dfrac{100.20\%}{98} = \dfrac{10}{49}$

$CuO + H_2SO_4 \to CuSO_4 + H_2O$

$n_{CuO} < n_{H_2SO_4}$ nên $H_2SO_4 dư

Theo PTHH :
$n_{CuSO_4} = n_{H_2SO_4\ pư} = n_{CuO} = 0,02(mol)$
$m_{dd} = 1,6 + 100 = 101,6(gam)$

Vậy :

$C\%_{CuSO_4} = \dfrac{0,02.160}{101,6}.100\% = 3,15\%$

$C\%_{H_2SO_4\ dư} = \dfrac{100.20\% - 0,02.98}{101,6}.100\% = 17,6\%$

CÂU 2

m_H2SO4=100.20%=20(g)

n_H2SO4=20/98=0,2(mol)

n_CuO=1,6/80=0,02(mol)

PTHH : CuO+H₂SO₄-->CuSO₄+H₂O(1)

bài        0,02    0,2         0,02       0,02             (mol)

có:0,02/1<0,2/1---->CuO hết,H₂SO₄ dư

từ pt(1)-->n_CuSO4=0,02(mol)--->m_CuSO4=0,02.160=3,2(g)

khối lượng dd sau pư là:1,6+100-0,02.18=101,24(g)

-->C_%(CuSO4)=3,2/101,24.100%=3,16%

CÂU 3

m_HCl=10.21,9%=2,19(g)

-->n_HCl=2,19/36,5=0,06(mol)

gọi tên KL là M.M_M=M(g/mol)

PTHH: MO+2HCl-->MCl₂+H₂O(1)

          0,03     0,06                       (mol)

từ pt 1-->n_MO=0,03(mol)

--->M_MO=2,4/0,03=80(g/mol)

--->M=80-16=64(g/mol)

--->M là Cu

Ta có: \(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)

PT: \(CuO+2HCl\rightarrow CuCl_2+H_2O\)

______0,2_____0,4_____0,2 (mol)

a, \(m_{CuCl_2}=0,2.135=27\left(g\right)\)

b, \(m_{HCl}=0,4.36,5=14,6\left(g\right)\Rightarrow C\%_{HCl}=\dfrac{14,6}{300}.100\%\approx4,867\%\)

c, Ta có: m _{dd sau pư} = 16 + 300 = 316 (g)

\(\Rightarrow C\%_{CuCl_2}=\dfrac{27}{316}.100\%\approx8,54\%\)

a) PTHH : \(Zn+H_2SO_4-->ZnSO_4+H_2\uparrow\)     (1)

                 \(ZnO+H_2SO_4-->ZnSO_4+H_2O\)   (2)

b) Theo pthh (1) : \(n_{Zn}=n_{H2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

=> \(m_{Zn}=0,1.65=6,5\left(g\right)\)

=> \(m_{ZnO}=22,7-6,5=16,2\left(g\right)\)

c) \(ZnO=\dfrac{16,2}{81}=0,2\left(mol\right)\)

Theo pthh (1) và (2) : \(\Sigma n_{H2SO4}=n_{Zn}+n_{ZnO}=0,1+0,2=0,3\left(mol\right)\)

=> \(C_{M\left(ddH2SO4\right)}=\dfrac{0,3}{0,1}=1,5M\)

a) PTHH :      (1)

                    (2)

b) Theo pthh (1) : ZnO=16,281=0,2(mol)ZnO=16,281=0,2(mol)

Theo pthh (1) và (2) : ΣnH2SO4=nZn+nZnO=0,1+0,2=0,3(mol)ΣnH2SO4=nZn+nZnO=0,1+0,2=0,3(mol)

=> tích đúng đê

Ta có: \(n_{H_2SO_4}=\dfrac{200.19,6\%}{98}=0,4\left(mol\right)\)

\(n_{Cu\left(OH\right)_2}=\dfrac{29,4}{98}=0,3\left(mol\right)\)

PT: \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)

Dung dịch A gồm: CuSO₄ và H₂SO₄ dư

\(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\)

\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)

Đề có cho dữ kiện gì liên quan đến dd NaOH không bạn nhỉ?

\(n_{H_2SO_4}=\dfrac{200.19,6}{100.98}=0,4mol\\ CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ n_{CuSO_4\left(A\right)}=n_{CuO}=n_{H_2SO_4}=0,4mol\\ n_{Cu\left(OH\right)_2}=\dfrac{29,4}{98}=0,3mol\\ CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\\\Rightarrow\dfrac{0,4}{1}>\dfrac{0,3}{1}\Rightarrow CuSO_4.pư.không.hết\)

\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)

0,3mol        0,6mol                                        0,3mol

\(m_{ddB}=0,4.80+200+0,6.40-29,4=226,6g\\ C_{\%Na_2SO_4\left(B\right)}=\dfrac{0,3.142}{226,6}\cdot100=18,8\%\)

a) \(n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\)

\(n_{HCl}=\dfrac{146.5\%}{36,5}=0,2\left(mol\right)\)

PTHH: CuO + 2HCl --> CuCl₂ + H₂O

Xét tỉ lệ: \(\dfrac{0,05}{1}< \dfrac{0,2}{2}\) => CuO hết, HCl dư

=> dd sau phản ứng chứa CuCl₂, HCl dư

b) 

PTHH: CuO + 2HCl --> CuCl₂ + H₂O

           0,05-->0,1------>0,05

m_{dd sau pư} = 4 + 146 = 150 (g)

\(\left\{{}\begin{matrix}C\%_{CuCl_2}=\dfrac{0,05.135}{150}.100\%=4,5\%\\C\%_{HCldư}=\dfrac{\left(0,2-0,1\right).36,5}{150}.100\%=2,433\%\end{matrix}\right.\)

b) 

PTHH: NaOH + HCl --> NaCl + H₂O

            CuCl₂ + 2NaOH --> 2NaCl + Cu(OH)₂

             0,05--------------------------->0,05

             Cu(OH)₂ --t^o--> CuO + H₂O

               0,05----------->0,05

=> \(a=m_{Cu\left(OH\right)_2}=0,05.98=4,9\left(g\right)\)

=> \(b=m_{CuO}=0,05.80=4\left(g\right)\)

\(a)CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ b)n_{CuO}=\dfrac{4}{80}=0,05mol\\ n_{H_2SO_4}=\dfrac{100.20}{100.98}=\dfrac{10}{49}mol\\ \Rightarrow\dfrac{0,05}{1}< \dfrac{10:49}{1}\rightarrow H_2SO_4.dư\\ n_{CuSO_4}=n_{H_2SO_4}=n_{CuO}=0,05mol\\ C_{\%CuSO_4}=\dfrac{0,05.160}{100+4}\cdot100=7,69\%\\ C_{\%H_2SO_4}=\dfrac{\left(10:49-0,05\right)98}{100+4}\cdot100=14,52\%\)

a) \(BaO+H_2O\rightarrow Ba\left(OH\right)_2\)

\(n_{Ba\left(OH\right)_2}=n_{BaO}=0,15\left(mol\right)\)

\(n_{BaCO_3}=\dfrac{23,64}{197}=0,12\left(mol\right)\)

Bảo toàn nguyên tố Ba => \(n_{Ba\left(HCO_3\right)_2}=0,15-0,12=0,03\left(mol\right)\)

Bảo toàn nguyên tố C: \(n_{CO_2}=0,12+0,03.2=0,18\left(mol\right)\)

=> \(V_{CO_2}=0,18.22,4=4,032\left(l\right)\)

b)Bảo toàn nguyên tố C : \(n_{CO_2}=n_{MgCO_3}+n_{CaCO_3}=a\left(mol\right)\)

Ta có : \(\dfrac{18,4}{100}< a< \dfrac{18,4}{84}\)

=> \(0,184< a< 0,22\)

\(n_{OH^-}=0,15.2=0,3\left(mol\right)\)

Lập T: \(\dfrac{0,3}{0,22}< T< \dfrac{0,3}{0,184}\)

=>\(1,36< T< 1,63\)

Do 1< \(1,36< T< 1,63\) <2

=> Phản ứng luôn tạo kết tủa